On the Occurrence of Clathrate Hydrates in Extreme Conditions:\ Dissociation Pressures and Occupancies at Cryogenic Temperatures with Application to Planetary Systems

We investigate the thermodynamic stability of clathrate hydrates at cryogenic temperatures from the 0 K limit to 200 K in a wide range of pressures, covering the thermodynamic conditions of interstellar space and the surface of the hydrosphere in satellites. Our evaluation of the phase behaviors is performed by setting up quantum partition functions with variable pressures on the basis of a rigorous statistical mechanics theory that requires only the intermolecular interactions as input.